Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO)(pyz).

Benjamin M Huddart,Jamie Brambleby,Tom Lancaster,Paul A Goddard,Fan Xiao,Stephen J Blundell,Francis L Pratt,John Singleton,Piero Macchi,Rebecca Scatena,Alyssa M Barton,Jamie L Manson

PHYSICAL CHEMISTRY CHEMICAL PHYSICS（2019）

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摘要

The quasi-one-dimensional molecule-based Heisenberg antiferromagnet Cu(NO3)(2)(pyz)(3) has an intrachain coupling J = 13.7(1) K () and exhibits a state of long-range magnetic order below T-N = 0.105(1) K. The ratio of interchain to intrachain coupling is estimated to be |J/J| = 3.3 x 10(-3), demonstrating a high degree of isolation for the Cu chains.

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关键词

magnetic order,exchange,quasi-one-dimensional,molecule-based

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