Synthesis, Solid-State Structure, and Bonding Analysis of a Homoleptic Beryllium Azide.

Dominik Naglav,Briac Tobey,Benjamin Lyhs,Beate Römer,Dieter Bläser, Christoph Wölper,Georg Jansen,Stephan Schulz

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION（2017）

引用 25|浏览2

暂无评分

摘要

[Ph4P](2)[Be(N-3)(4)] (1) and [PNP](2)[Be(N-3)(4)] (2; PNP= Ph3PNPPh3) were synthesized by reacting Be(N-3)(2) with [Ph4P]N-3 and [PNP]N-3. Compound 1 represents the first structurally characterized homoleptic beryllium azide. The electronic structure and bonding situation in the tetraazidoberyllate dianion [Be(N-3)(4)](2-) were investigated by quantum-chemical calculations (NPA, ELF, LOL).

查看译文

关键词

azides,beryllium,crystal structures,main group elements,quantum-chemical calculations

AI 理解论文

溯源树

样例

生成溯源树，研究论文发展脉络

Chat Paper

正在生成论文摘要