Chirally Sensitive Collision Induced Dissociation Of Proton-Bound Diastereomeric Complexes Of Tryptophan And 2-Butanol

Oleksii Rebrov,Kostiantyn Kulyk,Mauritz Ryding,Richard D. Thomas,Einar Uggerud,Mats Larsson

CHIRALITY（2017）

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摘要

In this work we report the stereo-dependent collision-induced dissociation (CID) of proton-bound complexes of tryptophan and 2-butanol. The dissociation efficiency was measured as a function of collision energy in single collision mode. The homochiral complex was found to be less stable against CID than a heterochiral one. Additional gas dependence measurements were performed with diastereomeric complexes that confirm the findings.

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关键词

amino acids,chiral recognition,collision induced dissociation,gas phase,mass spectrometry

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