The crystal structure of a new polymorph of hexa-aqua-nickel(II) bis-(6-oxo-1,6-di-hydro-pyridine-3-carboxyl-ate).
Acta crystallographica. Section E, Crystallographic communications(2015)
摘要
In a new polymorph of the title salt, [Ni(H2O)6](C6H4NO3)2, the metal atom of the cationic complex lies on a symmetry centre and is coordinated by six water molecules to provide a quite regular octahedral coordination environment. These cations interact with 6-oxo-1,6-dihydropyridine-3-carboxylate anions through electrostatic interactions and by means of O—H⋯O and N—H⋯O hydrogen bonds involving the carboxylate, keto and protonated imine groups of the anion, and the coordinating water molecules from the cationic complex entity to generate a supramolecular three-dimensional architecture. The previously reported polymorph of this compound presents a network of hydrogen bonds, in which the organic anions establish mutual hydrogen-bonding interactions involving their keto and protonated imine groups.
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关键词
6-oxo-1,6-dihydropyridine-3-carboxylate anion,crystal structure,hydrogen bonding,polymorph
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