Olefin Preparation Via Palladium-Catalyzed Oxidative De-Azotative And De-Sulfitative Internal Cross-Coupling Of Sulfonylhydrazones

Hongyu Tan,Ioannis Houpis,Renmao Liu,Youchu Wang,Zhilong Chen

Organic letters（2015）

引用 17|浏览2

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摘要

A novel reactivity of sulfonylhydrazones under Pd catalysis is described, where SO2 and N-2 are formally extruded to afford the product of an apparent internal coupling reaction. The reaction is effective with both carbocyclic and heterocyclic aromatic precursors.

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