Copper-catalyzed arene amination in pure aqueous ammonia

Mio Takagi,Ayako Watanabe,Shigeo Murata,Ryo Takita

Organic & Biomolecular Chemistry（2019）

引用 13|浏览7

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摘要

A simple protocol for copper-catalyzed arene amination using aqueous ammonia without any additional ligands and organic coordinating solvents has been developed. The reaction pathway via a Cu(I)/Cu(III) mechanism is proposed based on the results of control experiments as well as DFT calculations.

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关键词

arene amination,pure aqueous ammonia,copper-catalyzed

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