Ultrathin ZIF-67 nanosheets as a colorimetric biosensing platform for peroxidase-like catalysis
Analytical and Bioanalytical Chemistry(2018)
Abstract
In this work, we report a zeolitic imidazolate framework (ZIF-67) which could catalyze 3,3′,5,5′-tetramethylbenzidine (TMB) to produce a yellow chromogenic reaction. ZIF-67 showed high peroxidase-like activity compared with copper-based metal−organic framework nanoparticles (Cu-MOF), zinc-based metal−organic framework nanoparticles (ZIF-8), and horseradish peroxidase (HPR). We discovered for the first time that the cobalt-based metal−organic framework nanoparticles possess intrinsic peroxidase-like activity without H 2 O 2 , which can be employed to quantitatively monitor the H 2 O 2. Graphical abstract ᅟ
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Key words
Chromogenic reaction, in the absence of H 2 O 2
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