PFTBT modified visible-blind ultraviolet photodetector with narrow detecting range and high responsivity.

A visible-blind ultraviolet (UV) photodetector (PD) based on TiO2/polyvinyl carbazole doped with poly {[2,7-(9-(20-ethylhexyl)-9-hexyl-fluorene])-alt-[5,50-(40,70-di-2-thienyl-20,10,30-benzothid-iazole)]} (PFTBT) was successfully fabricated. The introduced PFTBT exhibits high absorbance in the UV region and high conductivity which increases the device absorbance and the efficiency of carrier mobility. Besides, PFTBT acts as traps which can increase the concentration of the majority carrier. Therefore, the doped device exhibits high responsivity and high specific detectivity with the value of 0.22 A W-1 and 1.78 x 10(12) Jones which respectively has a 3.6 and 2.6 times greater enhancement than the device without doping. The response time is also improved from 27 ms to 22 ms. Owing to the different absorbances that the materials have, the PD has a narrow detection range from 320 nm to 340 nm which is helpful to the study of the specific wavelength. In other words, the research provides a potential way to fabricate practical high-performance UVPDs.