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Visible light-mediated difluoroalkylation of electron-deficient alkenes.

Vyacheslav I Supranovich,Vitalij V Levin,Marina I Struchkova,Jinbo Hu,Alexander D Dilman

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY（2018）

Cited 14|Views21
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Abstract
A method for the reductive difluoroalkylation of electron-deficient alkenes using 1,1-difluorinated iodides mediated by irradiation with blue light is described. The reaction involves radical addition of 1,1-difluorinated radicals at the double bond followed by hydrogen atom transfer from sodium cyanoborohydride.
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Key words
difluoroalkylation,organofluorine compounds,radical addition,visible light
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