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NaI-mediated divergent synthesis of isatins and isoindigoes: a new protocol enabled by an oxidation relay strategy.

Hong-Hua Zhang,Yong-Qiang Wang,Long-Tao Huang,Long-Qing Zhu,Yi-Yue Feng,Ying-Mei Lu,Quan-Yi Zhao,Xue-Qiang Wang,Zhen Wang

CHEMICAL COMMUNICATIONS（2018）

Cited 22|Views5
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Abstract
A new approach for the synthesis of isatins and isoindigoes by an inexpensive and environmentally friendly NaI-mediated transformation is disclosed. The selectivity could be switched by simply varying the solvent, and isatins (using THF) and isoindigoes (using DMSO) could be obtained in moderate to excellent yields.
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Key words
isatins,isoindigoes,oxidation,divergent synthesis,nai-mediated
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