Facile Synthesis Of 3-Amido-Dienynes Via A Tandem -Propargylation-Isomerization Of Chiral Allenamides And Their Applications In Diels-Alder Cycloadditions

Zhi-Xiong Ma,Li-Chao Fang, Bryan J. Haugen, Daniel Bruckbauer,John B. Feltenberger,Richard P. Hsung

SYNLETT（2017）

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摘要

A series of interesting 3-amido-dienynes was synthesized via tandem -propargylation-isomerization of chiral allenamides with moderate E/Z ratio. Reactivities of E and Z isomers were examined.

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关键词

allenamide, tandem, 3-amido-dienyne, propargylation, Diels-Alder reaction, Pauson-Khand reaction, electrocyclization

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