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Evidence That Trimethyllysine Hydroxylase Catalyzes the Formation of (2S,3S)‑3-Hydroxy‑Nε‑trimethyllysine

Y Vijayendar Reddy,Abbas H K Al Temimi,Paul B White,Jasmin Mecinović

Organic Letters（2017）

Cited 9|Views2
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Abstract
Trimethyllysine hydroxylase (TMLH) is an Fe­(II) and 2-oxoglutarate (2OG) dependent oxygenase involved in the biomedically important carnitine biosynthesis pathway. A combination of synthetic and NMR studies provides direct evidence that human TMLH catalyzes the stereoselective conversion of (2S)-Nε-trimethyllysine to (2S,3S)-3-hydroxy-Nε-trimethyllysine.
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trimethyllysine hydroxylase catalyzes
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