Dichlorotrifluoromethoxyacetic Acid: Preparation And Reactivity

Riadh Zriba,Alaric Desmarchelier,Frederic Cadoret,Sebastien Bouvet,Anne-Laure Barthelemy,Bruce Pegot,Patrick Diter,Guillaume Dagousset,Jean-Claude Blazejewski,Elsa Anselmi,Yurii Yagupolskii,Emmanuel Magnier

MOLECULES（2017）

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摘要

We describe the first gram scale preparation of the reagent dichlorotrifluoromethoxyacetic acid. This stable compound is obtained in five steps starting from the cheap diethylene glycol. The reactivity of the sodium salt of this fluorinated acid was also tested and allowed the preparation of new amides.

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关键词

fluorine,trifluoromethoxy,amides

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