Magnetic Cu-MOFs embedded within graphene oxide nanocomposites for enhanced preconcentration of benzenoid-containing insecticides.

Hybrid magnetic nanocomposites based on Cu-MOFs, graphene oxide (GO), and Fe3O4 nanoparticles (NPs) were prepared via chemical bonding approach, which GO were used as platforms to load nanostructured Cu-MOFs and Fe3O4 NPs. The composite features both magnetic separation characteristics and high MOFs porosity, making it an excellent adsorbent for magnetic solid-phase extraction (MSPE). The as-synthesized nanocomposites are characterized by XRD, TGA, SEM, TEM, nitrogen adsorption-desorption analysis and FT-IR spectroscopy. The composites are used in MSPE of six aromatic insecticides from various real samples prior to their quantification by HPLC. Amount of adsorbent, extraction times, extraction temperature, desorption times and oscillation rate are optimized. Under the optimal conditions, the method has a relative standard deviations (RSDs) of 1.9-2.7%, and good linearity (correlation coefficients higher than 0.9931). The low LOD and LOQ for six insecticides are found to be 0.30-1.58μgL-1 and 1.0-5.2μgL-1, respectively. The RSDs of within batch extraction are 1.6-9.5% and 3.9-12% for batch to batch extraction. The experimental results suggest that the nanocomposites have potential application for removal of hazardous pollutants from effluents.