Task-specific design of a hierarchical porous aromatic framework as an ultrastable platform for large-sized catalytic active site binding.
CHEMICAL COMMUNICATIONS(2018)
Abstract
An amine-tagged hierarchical porous aromatic framework PAF70-NH2 with ultra-stability and narrowly distributed mesopores was synthesized. PAF70-NH2 has high potential for covalently immobilizing a relatively large-sized catalyst inside its pores. Thiswork gave a perfect example of using PAF70-NH2 as a platform for completely recyclable heterogeneous organocatalysis.
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Key words
Metal-Organic Frameworks,Porous Materials
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