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Palladium(Ii)-Stabilized Pyridine-2-Diazotates: Synthesis, Structural Characterization, And Cytotoxicity Studies

Alexander G Tskhovrebov,Anna A Vasileva,Richard Goddard,Tina Riedel,Paul J Dyson,Vladimir N Mikhaylov,Tatiyana V Serebryanskaya,Viktor N Sorokoumov,Matti Haukka

INORGANIC CHEMISTRY（2018）

Cited 28|Views20
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Abstract
Well-defined diazotates are scarce. Here we report the synthesis of unprecedented homoleptic palladium(II) diazotate complexes. The palladium(II)-mediated nitrosylation of 2-aminopyridines with NaNO2 results in the formation of metal-stabilized diazotates, which were found to be cytotoxic to human ovarian cancer cells.
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