Manganese-Mediated Linkage of Perchlorate to Aminotetrazoles Produces Twice the Energy Density of the Unmetalated Salt.

New regimes of energy density in energetic materials may be achieved by replacement of oxidizing nitro groups with stronger oxidants such as oxychlorine species. We report the energetic material 1,3-di-tert-butyltetrazolium-5-imidoperchloratomanganese(II) 2, which crystallizes as an oligomeric cubane cluster. Bomb calorimetry on the amorphous, solvent-free phase gives an energy density of at least 40 +/- 3 MJL(-), higher than hydrocarbon combustion in air, more than twice that of traditional energetic nitramines, and approximate to 70% higher than that of the unmetalated tetrazolium perchlorate salt without metal linkage. The effects of solid-state structure, charge, and lattice energy on the energy of 2 are discussed.