A naphthalene benzimidazole-based chemosensor for the colorimetric and on-off fluorescent detection of fluoride ion.
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy(2017)
摘要
A novel naphthalene benzimidazole (NBI)-based chemosensor (D2) was developed for fluoride ion (F−) detection. The absorption spectrum of D2 changed dramatically from yellow to blue in the visible region accompanied with a 225nm red shift of its absorption maximum upon the addition of F− in DMSO. D2 also exhibited a fluorescence turn-off response towards the fluoride ion. The emission intensity of D2 decreased drastically along the increasing F− concentration and the detection limit for F− was as low as 3.2×10−9mol/L. 1H NMR and HRMS-ESI results indicated that the formation of NBI-O− through the desilylation reaction of F− with NBI-OSi was responsible for the spectral changes. Overall, this kind of NBI-type molecules represent a new type chemosensor for the spectral detection of fluoride ion in solution.
更多查看译文
关键词
Fluoride ion,Chemosensor,Naphthalene benzimidazole,Fluorescence quenching,Desilylation reaction
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要