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Boron Trifluoride Gas Adsorption In Metal-Organic Frameworks

Paul W Siu,John P Siegfried,Mitchell H Weston,Patrick E Fuller,William Morris,Christopher R Murdock,William J Hoover,Rachelle K Richardson,Stephanie Rodriguez,Omar K Farha

INORGANIC CHEMISTRY（2016）

Cited 14|Views32
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Abstract
Coordinatively unsaturated metal organic frameworks (MOFs) were studied for boron trifluoride (BF3) sorption. MOF-74-Mg, MOF-74-Mn, and MOF-74-Cu show high initial uptake (below 6.7 X 10(-3) bar) with negligible deliverable capacity. The BF3 isotherm of MOF-74-Cu exhibits gradual uptake up to 0.9 bar and has a deliverable gravimetric capacity that is more than 100% higher than activated carbon. Two other Cu2+ MOFs, MOF-SOS and HKUST-1, have slightly lower deliverable capacities compared to MOF-74-Cu.
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Key words
gas adsorption,metal–organic frameworks,boron
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