Palladium-Catalyzed Direct Cross-Coupling of Carboranyllithium with (Hetero)Aryl Halides.

Ju-You Lu,Hong Wan,Jianwei Zhang,Zhixuan Wang,Yang Li,Yongmei Du,Chunying Li,Zhao-Tie Liu,Zhong-Wen Liu,Jian Lu

CHEMISTRY-A EUROPEAN JOURNAL（2016）

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摘要

A palladium-catalyzed direct C-arylation reaction of readily available cage carboranyllithium reagents with aryl halides has been developed for the first time. This method is applicable to a wide range of aryl halide substrates including aryl iodides, aryl bromides, and heteroaromatic halides.

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关键词

C(cage)-C(sp(2)) formation,carboranyllithium,cross-coupling,direct C-arylation,palladium

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