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TEMPO-mediated oxidation on galactomannan: Gal/Man ratio and chain flexibility dependence.

Caroline Novak Sakakibara,Maria Rita Sierakowski,Neoli Lucyszyn,Rilton Alves de Freitas

Carbohydrate Polymers（2016）

Cited 21|Views1
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Abstract
•Guar and locust bean galactomannans carboxylation were performed with catalyst TEMPO.•TEMPO-mediated reaction on both GMs shows a preference to oxidize Man.•TEMPO-mediated oxidation follows a first order kinetics, higher to LBG than GG.•Man OH-6 accessibility in LBG could be related with a two times faster reaction than GG.
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Key words
Selective C-6 oxidation,TEMPO,Galactomannans,Guar gum,Locust bean gum,HPSEC
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