Self-assembly of pseudo-rotaxane and rotaxane complexes using an electrostatic slippage approach.
CHEMICAL COMMUNICATIONS(2016)
摘要
The protonation of a cyclic tertiary amine, integrated into the structure of a dumbbell-shaped guest molecule, accelerates the sliding of the guest through the cavity of a crown ether macrocycle to yield a stable pseudo-rotaxane complex. The use of an amine with the appropriate ring size followed by a proton transfer reaction leads to the formation of an interlocked rotaxane species.
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关键词
pseudo-rotaxane complexes,self-assembly
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