Tuning Up An Electronic Structure Of The Subphthalocyanine Derivatives Toward Electron-Transfer Process In Noncovalent Complexes With C-60 And C-70 Fullerenes: Experimental And Theoretical Studies
INORGANIC CHEMISTRY(2016)
摘要
Noncovalent pi-pi interactions between chloroboron subphthalocyanine (1), 2,3-subnaphthalocyanine (3), 1,4,8,11,15,18-(hexathiophenyl)subphthalocyanine (4), or 4-tert-butylphenoxyboron subphthalocyanine (2) with C-60 and C-70 fullerenes were studied by UVvis and steady-state fluorescence spectroscopy, as well as mass (APCI, ESI, and CSI) spectrometry. Mass spectrometry experiments were suggestive of relatively weak interaction energies between compounds 14 and fullerenes. The formation of a new weak charge-transfer band in the NIR region was observed in solution only for subphthalocyanine 4 when titrated with C-60 and C-70 fullerenes. Molecular structures of the subphthalocyanines 2 and 4 as well as cocrystallite of 4 with C-60 fullerene (4 center dot center dot center dot C60) were studied using X-ray crystallography. One of the C-60 fullerenes in the crystal structure of 4 center dot center dot center dot C60 was found in the concave region between two subphthalocyanine cores, while the other three fullerenes are aligned above individual isoindole fragments of the aromatic subphthalocyanine. The excited-state dynamics in noncovalent assemblies were studied by transient absorption spectroscopy. The time-resolved photophysics data suggest that only electron-rich subphthalocyanine 4 can facilitate an electron-transfer to C-60 or C-70 fullerenes, while no electron-transfer from the photoexcited receptors 13 to fullerenes was observed in UVvis and transient spectroscopy experiments. DFT calculations using the CAM-B3LYP exchange-correlation functional and the 6-31+G(d) basis set allowed an estimation of interaction energies for the noncovalent 1:1 and 1:2 (fullerene:subphthalocyanine) complexes. Theoretical data suggest that the weak (similar to 3.510.5 kcal/mol) van der Waals-type interaction energies tend to increase with an increase of the electron density at the subphthalocyanine core with compound 4 being the best platform for noncovalent interactions with fullerenes. DFT calculations also indicate that 1:2 (fullerene:subphthalocyanine) noncovalent complexes are more stable than the corresponding 1:1 assemblies.
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关键词
Chirality-Sensing Supramolecular Systems
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