Sensitive and selective fluorescence detection of aqueous uranyl ions using water-soluble CdTe quantum dots

Journal of Radioanalytical and Nuclear Chemistry(2018)

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摘要
Herein we report a fluorescent method for sensitive and selective detection of uranyl ions using CdTe quantum dots functionalized with mercaptopropionic acid, which the fluorescence of the quantum dots could be quantitatively quenched through electron transfer mechanism. The detection limit of the method was estimated to be 4 nM, less than the maximum allowed content of 130 nM for uranyl in drinking water defined by the U.S. Environmental Protection Agency. Furthermore, the probe was successfully applied in detection of uranyl ions in real samples, demonstrating its potential practical applications for monitoring of uranyl ions in environment.
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关键词
Cadmium telluride quantum dots,Uranyl ions,Fluorescence quenching,Electron transfer mechanism,Masking agent
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