Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged M II (M = Mn, Ni) coordination polymers.
DALTON TRANSACTIONS(2018)
Abstract
M-II (M = Mn, Ni) coordination frameworks, singly linked by end-on azide ligands, were prepared by employing the long, flexible spacer ligand, p-XBP4. These two-dimensional layer structures underwent reversible crystal-to-amorphous phase transformations during the hydration-dehydration process. Moreover, the magnetic nature changes from antiferromagnetic to ferromagnetic coupling when moving from Mn to Ni.
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Key words
coordination polymers,crystal-to-amorphous,azide-bridged
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