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CuOTf-mediated intramolecular diborene hydroarylation.

Sunewang Rixin Wang,Merle Arrowsmith,Holger Braunschweig,Rian D Dewhurst,Valerie Paprocki,Lena Winner

CHEMICAL COMMUNICATIONS（2017）

Cited 23|Views7
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Abstract
Upon complexation to CuOTf, a PMe3-stabilized bis(9-anthryl) diborene slowly undergoes an intramolecular hydroarylation reaction at room temperature. Subsequent triflation of the B-H bond with CuOTf, followed by a PMe3 transfer, finally yields a cyclic sp(2)-sp(3) boryl-substituted boronium triflate salt.
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Key words
intramolecular diborene hydroarylation,cuotf-mediated
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