Stimuli-responsive NLO properties of tetrathiafulvalene-fused donor-acceptor chromophores.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS(2017)
摘要
The second-order nonlinear optical (NLO) properties of two tetrathiafulvalene (TTF)-fused electron donor-acceptor dyads have been determined using the Electric Field Induced Second Harmonic generation (EFISH) technique and theoretically rationalized. Dyads TTF-dppz (1) and TTF-BTD (2) were obtained by direct fusion of a TTF electron donor unit either with a dipyrido[3,2-a:20,30-c]phenazine (dppz) or a benzothiadiazole (BTD) electron acceptor moiety. Dyad 1 acts as a reversible acido-triggered NLO switch by protonation/deprotonation at two nitrogen atoms of the dppz acceptor moiety induced by sequential exposure to HCl and ammonia vapors. Dyad 2, on the other hand, displays redox-tunable NLO properties upon two consecutive oxidations to its radical cation 2(+center dot) and dication 2(2+) species. The resulting final dication 2(2+) exhibits an inversion of the sign of beta(0), due to a completely inverted distribution of the frontier molecular orbitals with respect to those of its neutral species, leading to a scarcely polar species in the excited state, as indicated by the theoretical calculations.
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关键词
donor–acceptor chromophores,stimuli-responsive,tetrathiafulvalene-fused
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