A practical chemo-enzymatic approach to highly enantio-enriched cyanohydrin acetates

Nuala M Maguire,Alan Ford,Sarah L Clarke,Kevin S Eccles,Simon E Lawrence,Maude Brossat,Thomas S Moody,Anita R Maguire

Tetrahedron: Asymmetry（2011）

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摘要

The preparation of enantiopure cyanohydrin acetates via enzymatic hydrolysis has been investigated by screening a range of biocatalysts and reaction conditions. Enzymatic resolution has been optimised through variation of the hydrolase biocatalyst and reaction conditions leading to synthetically useful routes to enantiopure cyanohydrin acetates.

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