Asymmetric hydrogenation of α-keto phosphonates with chiral phosphine–phosphoramidite ligands
Tetrahedron: Asymmetry(2015)
摘要
Rh-catalyzed asymmetric hydrogenation of challenging α-keto phosphonates has been developed. With a new chiral phosphine–phosphoramidite ligand, a wide range of α-keto phosphonates were hydrogenated to afford the corresponding (R)-α-hydroxy phosphonates with moderate to good enantioselectivities (up to 87% ee).
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