Cerium metal- mediated Reformatsky-type reaction with ethyl bromosuccinate for the synthesis of novel paraconic acid analogs

Shirley M M Rodrigues,Viviani Nardini,Mauricio Gomes Constantino,Gil Valdo J Da Silva

Tetrahedron Letters（2012）

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摘要

The treatment of cerium metal with ethyl bromosuccinate (1) forms the stabilized organolanthanoid intermediate (2), which reacts with carbonyl compounds in a Reformatsky-type reaction, under mild conditions, to produce functionalized γ-substituted paraconic acids (4) in good yields.

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关键词

Ethyl bromosuccinate,Cerium metal,Reformatsky-type reaction,Paraconic acids

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