A divergent/convergent approach to dolabriferol: the Kornblum–DeLaMare enantiomeric resolution

Michael R Gesinski,William E Brenzovich,Steven T Staben, Dianne J Srinilta,F Dean Toste

TETRAHEDRON LETTERS（2015）

引用 11|浏览15

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摘要

Several protected precursors of the polypropionate metabolite dolabriferol have been synthesized. A novel Kornblum-DeLaMare enantiomeric resolution was used to form two fragments of the natural product from a common precursor. (C) 2015 Elsevier Ltd. All rights reserved.

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关键词

Convergent synthesis,Divergent synthesis,Kinetic resolution,Kornblum-DeLaMare,Organocatalysis

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