A tandem hetero Diels–Alder/Mannich approach for the synthesis of a versatile hexahydro-2 H -pyrano[3,2- c ]pyridin-4(3 H )-one core

Ralph P Robinson,Agustin Casimirogarcia,Sidney Liang,Dennis P Anderson,Andrew C Flick

Tetrahedron Letters（2013）

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摘要

The synthesis of a highly functionalizable hexahydro-2H-pyrano[3,2-c]pyridin-4(3H)-one core is described and sequentially involves a hetero-Diels Alder (HDA) reaction and an intramolecular Mannich reaction resulting in selective formation of the trans-fused ring geometry.

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关键词

Mannich,Hetero Diels–Alder (HDA),Azadecalone,trans-Fused azadecalin

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