Chemically bonded cationic β-cyclodextrin derivatives as chiral stationary phases for enantioseparation applications
Tetrahedron Letters（2012）
Abstract
Vinylene-functionalized cationic β-cyclodextrins are co-polymerized with vinylized silica in the presence of AIBN and conjugated monomers. The chemically immobilized cationic β-cyclodextrins were thereafter applied as chiral stationary phases in packed column supercritical fluid chromatography and demonstrated good and reproducible enantioseparations of racemic pharmaceutical compounds.
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Key words
Cationic β-cyclodextrin,Co-polymerization,Chiral stationary phase,Supercritical fluid chromatography
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