Phase equilibrium measurements for clathrate hydrates of flue gas (CO 2 +N 2 +O 2 ) in the presence of tetra-n-butyl ammonium bromide or tri-n-butylphosphine oxide
The Journal of Chemical Thermodynamics（2015）
摘要
•Semi-clathrate hydrate phase equilibria for ternary gas mixture of CO2, N2, and O2 are reported.•An isochoric pressure-search method was used.•TBPO outperforms TBAB in promoting the formation of flue gas hydrate.
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关键词
Semi-clathrate hydrate,Phase equilibrium,Carbon dioxide capture,Hydrate promoter,Gas separation
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