Electrocatalytic fluoroalkylation of olefins. Nickel-catalyzed polyfluoroalkylation of allylisocyanurates
Russian Chemical Bulletin(2013)
Abstract
Electrochemical co-reduction of allylisocyanurates and polyfluoroalkyl halides in the presence of nickel complexes with α-diimine ligands results in the addition of the polyfluoroalkyl group to the C=C bond followed by dimerization of the intermediate adducts.
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Key words
polyfluoroalkylation,polyfluoroalkyl halides,electroreduction,catalysis,allylisocyanurates,nickel complexes,bipyridine
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