Gan Lateral Overgrowth By Hydride Vapor Phase Epitaxy Through Nanometer-Size Channels Fabricated With Nanoimprint Lithography

Epitaxial lateral overgrowth (ELO) has been used for reducing the dislocation density to grow high-quality GaN crystals. In conventional ELO, micrometer-size channels formed on a mask material such as SiO2, where GaN growth starts, are generally used. In the present study, ELO through nanometer-size (50-80 nm) channels is investigated to improve the dislocation reduction ability. Channels are fabricated using nanoimprint lithography and dry etching. We demonstrate for the first time successful hydride vapor phase epitaxy (HVPE)-based GaN ELO growth through nanochannels. In the growth interface, distinct facet structures appear and coalescence between neighboring facets proceeds. The surface of a 20-mu m-thick GaN layer becomes flat by the valleys between facet structures being buried. The dislocation density is shown to decrease to approximately 5 x 10(7) cm(-2) for a 20-mu m-thick GaN layer on sapphire. Photoluminescence measurements show a decay time of over 3 times longer than that of a conventional metalorganic chemical vapor deposition (MOCVD) template. (C) 2013 The Japan Society of Applied Physics