Infinite dilution activity coefficients and Henry's law constants of compounds in water using the inert gas stripping method

Fluid Phase Equilibria(2013)

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摘要
Henry's law constants and infinite dilution activity coefficients were measured for toluene, 1-butanol, anisole, 1,2-difluorobenzene, 4-bromotoluene, 1,2,3-trichlorobenzene, and 2,4-dichlorotoluene in water using the inert gas stripping method at ambient pressure (approximately 86.2kPa) and at temperatures between 281.15K and 323.15K. Fugacity ratios, required to determine infinite dilution activity coefficients for the solid solutes, were calculated from literature values for the heat of fusion and the liquid and solid heat capacities. Chemicals were chosen based on missing or conflicting data from the literature.
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关键词
Henry's law constant,Infinite dilution activity coefficient,Inert gas stripping
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