Synthesis, growth, and characterization of a new NLO material 3-(2,3-dimethoxyphenyl)-1-(pyridin-2-yl)prop-2-en-1-one
Journal of Molecular Structure(2012)
摘要
3-(2,3-Dimethoxyphenyl)-1-(pyridin-2-yl)prop-2-en-1-one (DMPP) a potential second harmonic generating (SHG) has been synthesized and grown as a single crystal by the slow evaporation technique at ambient temperature. The structure determination of the grown crystal was done by single crystal X-ray diffraction study. DMPP crystallizes with orthorhombic system with cell parameters a=20.3106(8)Å, b=4.9574(2)Å, c=13.4863(5)Å, α=90°, β=90°, γ=90° and space group Pca21. The crystals were characterized by FT-IR, thermal analysis, UV–vis–NIR spectroscopy and SHG measurements. Various functional groups present in DMPP were ascertained by FTIR analysis. DMPP is thermally stable up to 80°C and optically transparent in the visible region. The crystal exhibits SHG efficiency comparable to that of KDP.
更多查看译文
关键词
Nonlinear,Crystal,Second harmonic generation
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要