Stereochemistry analysis and comparison of two C(3)-alkyl substituted cyclohexonedicarboxylates with their C(3)-aryl substituted analogues
Journal of Molecular Structure(2016)
Abstract
Two representative C(3)-alkyl substituted cyclohexonedicarboxylates (4a and 4b) were synthesized and their conformational features were investigated by single crystal X-ray crystallography for the first time. These stereochemistry results of 4a and 4b were compared with those obtained from the earlier research of C(3)-aryl substituted analogues (1–3).
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Key words
Cyclohexonedicarboxylate,β-keto ester,Configuration,X-ray crystallographic analysis
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