Electronic and conformational features of derivatives of meso- thien-2-ylporphyrins on protonation and perbromination

Journal of Molecular Structure（2015）

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摘要

•Electronic effects of meso-substituents on the properties of the porphyrins.•Effect of orientation of meso-substituents on the electronic properties of porphyrins.•Electronic properties of protonated and perbrominated thienylporphyrins.•Structural aspects of thienylporphyrins on protonation and perbromination.

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关键词

Thienylporphyrins,Conformation,Protonation,Extended conjugation,Sterics,Imino hydrogen

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