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In-depth NMR and IR study of the proton transfer equilibrium between [{(MeC(CH2PPh2)3}Ru(CO)H2] and hexafluoroisopropanol

V I Bakhmutov,Ekaterina V Bakhmutova,Natalia V Belkova,Claudio Bianchini,Lina M Epstein,Dante Masi,Maurizio Peruzzini,Elena S Shubina,Evgenii V Vorontsov,Fabrizio Zanobini

Canadian Journal of Chemistry（2011）

Cited 55|Views8
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Abstract
The (carbonyl)dihydride complex [(triphos)Ru(CO)H2] (2) has been synthesized by reaction of the ruthenate [(triphos)RuH3]K (triphos = MeC(CH2PPh2)3) with ethanol saturated with CO. A single crystal...
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Key words
proton transfer equilibrium,hexafluoroisopropanol,nmr,in-depth
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