Thermodynamic stability conditions, methane enrichment, and gas uptake of ionic clathrate hydrates of mine ventilation air

Chemical Engineering Journal（2015）

引用 20|浏览3

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摘要

•Hydrate-based CH4 removal from mine ventilation air was studied.•An isochoric pressure-search method was used to measure hydrate stability condition.•3-fold methane enrichment was obtained at a relatively low chemical dosage.

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关键词

Ventilation air methane,Ionic clathrate hydrate,Tri-n-butylphosphine oxide,Tetra-n-butyl ammonium bromide,Phase equilibrium

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