Sterically Congested Chiral N-Acetyl 2-Oxazolidinone as Acetyl Enolate Equivalents in Stereoselective Aldol Reactions.

Koreichi Kimura,Tadao Ishizuka,Keiko Otsuka,Takehisa Kunieda

CHEMICAL & PHARMACEUTICAL BULLETIN（1994）

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摘要

Sterically constrained and highly congested N-acetyl-DMAOx (1a) serves well as a useful chiral acetyl enolate equivalent which permits a diastereoselective and direct approach to 'acetate' aldols (2) including statine derivative.

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关键词

CHIRAL 2-OXAZOLIDINONE AUXILIARY,ACETYL ENOLATE EQUIVALENT,ALDOL REACTION,STATINE

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