Deep HDS of FCC gasoline over alumina supported CoMoS catalyst: Inhibiting effects of carbon monoxide and water

Applied Catalysis B: Environmental(2016)

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摘要
•Weak decrease of the HDS and HYD activity of the gasoline model feed in the presence of water, and partially irreversible.•Main inhibiting effect induced by CO rather than water, but completely reversible.•Higher adsorption energy of CO than water quantified by DFT calculations.
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关键词
Hydrodesulfurization,Olefin hydrogenation,FCC gasoline,Carbon monoxide,CoMoS/Al2O3,Edge sites,Density functional theory
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