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Unusual adsorption and desorption behaviors of NO and CO on nanoporous nickel phosphate VSB-5: In situ FT-IR and TPD study

Zhi Chen,Dantong Zhou,Tong Gao,Weihua Shen,Xiaoping Dong,Shuichi Naito,Laishun Qin,Yuexiang Huang

Catalysis Today（2015）

Cited 9|Views16
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Abstract
Large amounts of NO can be adsorbed on Ni2+ sites in the pores of VSB-5. The adsorption may be promoted by heating process helping NO to reach some inaccessible sites at lower temperatures, which demonstrates an unusual adsorption character.
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Key words
Nanoporous nickel phosphate VSB-5,NO adsorption/desorption,CO adsorption/desorption,Isotopic labeled adsorption,In situ FTIR,TPD
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