Kinetics Of Photoinduced Matter Transport Driven By Intensity And Polarization In Thin Films Containing Azobenzene

We investigate the kinetics of photoinduced deformation phenomena in azobenzene-containing thin solid films. We show that a light intensity pattern and a light polarization pattern produce two distinct material transport processes whose direction and kinetics can be independently controlled. The kinetics of the intensity-driven deformation scales with the incoming light power while the kinetics of the polarization-driven mass transport scales with the amplitude of the electromagnetic field pattern. We conclude that these two processes are fully independent one from the other and originate from two different microscopic mechanisms.