Design and study of an atmospheric pressure ion funnel by computer simulations
Rapid Communications in Mass Spectrometry(2015)
Abstract
RATIONALE: An atmospheric pressure ion funnel (APIF) has been developed to transfer and focus ions at atmospheric pressure. This ion funnel can be used as an interface connecting the ion source and the mass spectrometer detector. METHODS: The APIF designs were studied mainly by using computer simulations. Different APIF configurations with various geometrical and electrical parameters were analyzed. Investigation of the electrical field and ion transmission characteristics of the APIF was carried out using SIMION 8.0. RESULTS: The APIF exhibits good ion-guiding performance with transmission efficiency of >90%. An approximate formula for determining the optimal parameters of the APIF has been derived by theoretical calculation. CONCLUSIONS: When both the geometrical and the electrical parameters are optimized, the APIF can provide high ion transmission efficiency. In addition, the proposed empirical formula is helpful in guiding the design of APIFs. Copyright (C) 2015 John Wiley & Sons, Ltd.
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Key words
IONIZATION MASS-SPECTROMETRY,ELECTROSPRAY-IONIZATION,SENSITIVITY,INTERFACE,TRANSMISSION,SIMION
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