Adsorbed film of n -tetradecylphosphocholine at the tetradecane/water interface studied by interfacial tensiometry and X-ray reflection

Shigeyoshi Hiraki,Tsuneaki Goto,Hajime Tanida, Kento Nitta,Toshiaki Ina,Tomoya Uruga,Hiroki Matsubara,Makoto Aratono,Takanori Takiue

Colloids and Surfaces A: Physicochemical and Engineering Aspects（2015）

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摘要

•The adsorbed C14PC film was examined by interfacial tensiometry and X-ray reflection.•C14PC molecules form bilayer with upside-down arrangement of PC groups.•Positive entropy change of adsorption is mainly due to the dehydration around C14PC.•Solute — solvent interaction makes hydrophobic chains of C14PC molecules more ordered.

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关键词

Adsorbed film,n-Tetradecylphosphocholine,Interfacial tensiometry,X-ray reflection,Bilayer,Dehydration

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