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Syntheses, crystal structures, luminescent properties of two new molecular solids with tetra(isothiocyanate)zinc(II) and substituted benzyl triphenylphosphonium cations

Huiqing Ye,Jialing Xie,Jiayu Yu,Qianting Liu,Shulin Dai,Wanquan Huang,Jiarong Zhou,Lemin Yang,Chunlin Ni

Synthetic Metals（2014）

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Abstract
•Two molecular solids containing [Zn(NCS)4]2− anion were synthesized and characterized.•The [Zn(NCS)4]2− anions in two molecular solids form 1D chain through weak S⋯S interaction.•The cations in 2 form a 1D column through CH⋯S, CH⋯O hydrogen bonds and p⋯π interaction.•Two molecular solids show strong fluorescence emission in the solid state at room temperature.
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Key words
Tetra(isothiocyanate)zinc(II) dianion,Substituted benzyl triphenylphosphonium,Crystal structure,Luminescent properties
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