Syntheses, crystal structures and magnetic properties of three new molecular solids based on bis(maleonitriledithiolate)copper(II) anion and 2-substituted benzyl triphenylphosphonium

Weiqiang Chen,Yelong Qian,Huatang Cai,Yanhui Pan,Manna Li, Xueni Lin,Xiaoxu Zheng,Jiarong Zhou,Lemin Yang,Chunlin Ni

Synthetic Metals（2014）

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摘要

•Three molecular solids containing [Cu(mnt)2]2− anion were synthesized and characterized.•There are weak CH⋯X, CH⋯S, CH⋯N, CH⋯Cu, CH⋯π and X⋯X interactions.•Three molecular solids form a 3D network structure, and show weak ferromagnetic coupling at 2.0–300K.

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关键词

2-Substituted benzyl triphenylphosphonium,Bis(maleonitriledithiolate)copper(II) anion,Weak interactions,Magnetic properties

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